Hi there, sorry I didn't realise that there were more messages in this topic added.
Yes, I did give up attempting to install the OS directly onto a USB flash drive and had a spare DVDRW disc lying around which I thought I would attempt to use. This did allow me to create a Pupsave file which I can now boot directly into and use. There are some minor issues like not having the language settings stick and I have to just change this each time.
I am still unsure as to by hibernation was enabled as when I do exit Windows it did power down and I do not have a screensaver enabled. @williams2 Yes, my PC Bios setting did have Fast Boot setting enabled.
However, the command provided did make a difference to me, it worked.
Glad you got it working in the end too!!