THIS IS OFFICIALLY SOLVED
To summarize:
ORIGINAL PROBLEM: "Can't boot from external usb drive". It's because the table created was GPT/UEFI and my desktop is set to Legacy boot because the internal SSDs were created using the MSDOS table just as @dimkr suspected.
SOLUTION: Recreating the table on the SSDs or flip-flopping between UEFI/Legacy bios setting is too much hassle. So, I re-created the table on the external usb drive to use MSDOS
RESULT: I am now making this post using the distro I'm testing, that is installed on the external usb drive
Thanks again to all. You all make learning computer FUN and easy. One last thing, speed performance of this usb external drive is surprisingly fast. Was expecting a bit slower than this. So, needless to say, I will be a happy distro tester. LOL